Radius Calculation
🔬 Bohr’s Model – Derivation of Atomic Radius
🔹 Key Assumptions
- Electron revolves in a circular orbit due to Coulombic attraction.
- Angular momentum is quantized: m × v × r = (n × h) / 2π
🔹 Step 1: Equating Forces
Electrostatic Force = Centripetal Force
(m × v²) / r = (1 / 4πε₀) × (Z × e²) / r²
🔹 Step 2: Angular Momentum Quantization
Given: m × v × r = (n × h) / (2π)
⇒ v = (n × h) / (2π × m × r)
🔹 Step 3: Substitution & Simplification
Substitute v into the force equation:
(m / r) × [ (n × h) / (2π × m × r) ]² = (Z × e²) / (4π × ε₀ × r²)
After simplifying, we get:
rₙ = (n² × h² × ε₀) / (π × m × Z × e²)
🔹 Final Formula
rₙ = (n² × a₀) / Z
Where: a₀ ≈ 0.529 Å is the Bohr radius for hydrogen.
🔬 Bohr’s Model – Derivation of Atomic Radius
🔹 Key Assumptions
- Electron revolves in a circular orbit due to Coulombic attraction.
- Angular momentum is quantized: m × v × r = (n × h) / 2π
🔹 Step 1: Equating Forces
Electrostatic Force = Centripetal Force
(m × v²) / r = (1 / 4πε₀) × (Z × e²) / r²
🔹 Step 2: Angular Momentum Quantization
Given: m × v × r = (n × h) / (2π)
⇒ v = (n × h) / (2π × m × r)
🔹 Step 3: Substitution & Simplification
Substitute v into the force equation:
(m / r) × [ (n × h) / (2π × m × r) ]² = (Z × e²) / (4π × ε₀ × r²)
After simplifying, we get:
rₙ = (n² × h² × ε₀) / (π × m × Z × e²)
🔹 Final Formula
rₙ = (n² × a₀) / Z
Where: a₀ ≈ 0.529 Å is the Bohr radius for hydrogen.
r = (n² * a₀) / Z
Where:
- r = radius of the electron's orbit
- n = principal quantum number (for the ground state, n = 1)
- Z = atomic number of the ion
- a₀ = Bohr radius (5.29 × 10⁻¹¹ m)
r = (1² * 5.29 × 10⁻¹¹) / 2 = 2.65 × 10⁻¹¹ m
The radius of the He+ ion is approximately 2.65 × 10⁻¹¹ m, or 26.5 picometers.
r = (n² * a₀) / Z
Where:
- r = radius of the electron's orbit
- n = principal quantum number (for the ground state, n = 1)
- Z = atomic number of the ion
- a₀ = Bohr radius (5.29 × 10⁻¹¹ m)
r = (1² * 5.29 × 10⁻¹¹) / 2 = 2.65 × 10⁻¹¹ m
The radius of the He+ ion is approximately 2.65 × 10⁻¹¹ m, or 26.5 picometers.
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