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🔬 Bohr’s Model – Derivation of Atomic Radius

🔹 Key Assumptions

  1. Electron revolves in a circular orbit due to Coulombic attraction.
  2. Angular momentum is quantized: m × v × r = (n × h) / 2π

🔹 Step 1: Equating Forces

Electrostatic Force = Centripetal Force

(m × v²) / r = (1 / 4πε₀) × (Z × e²) / r²

🔹 Step 2: Angular Momentum Quantization

Given: m × v × r = (n × h) / (2π)

v = (n × h) / (2π × m × r)

🔹 Step 3: Substitution & Simplification

Substitute v into the force equation:

(m / r) × [ (n × h) / (2π × m × r) ]² = (Z × e²) / (4π × ε₀ × r²)

After simplifying, we get:

rₙ = (n² × h² × ε₀) / (π × m × Z × e²)

🔹 Final Formula

rₙ = (n² × a₀) / Z

Where: a₀ ≈ 0.529 Å is the Bohr radius for hydrogen.

Bohr's Theory - Radius of He+
Calculate the radius of He+ according to Bohr's theory
The short formula to calculate the radius of an electron's orbit in a hydrogen-like atom (such as He+) according to Bohr's theory is:

r = (n² * a₀) / Z

Where:
  • r = radius of the electron's orbit
  • n = principal quantum number (for the ground state, n = 1)
  • Z = atomic number of the ion
  • a₀ = Bohr radius (5.29 × 10⁻¹¹ m)
For He+, n = 1 and Z = 2, so the radius r is:

r = (1² * 5.29 × 10⁻¹¹) / 2 = 2.65 × 10⁻¹¹ m

The radius of the He+ ion is approximately 2.65 × 10⁻¹¹ m, or 26.5 picometers.


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